I work in agriculture research. It has its ups and downs, but the pay is pretty decent and I pretty good vacations. The only problem is that I'm planting during spring seasons and harvesting during October (on a usual year). That keeps me out of most rifle seasons, which is why I picked up the stick and string and haven't looked back. The company I work for is called Monsanto, but Pioneer and Syngenta are other companies that do the exact same thing I do. We have locations from California to New York and from Canada to Mexico and actually all over the world so you can move wherever you want as long as there is some agriculture. Not a bad gig that way.
My brother is a deputy for the Sheriff department in NW New Mexico and can typically take off a little easier around hunting season than I can, but he also has to dodge bullets and break up fights which doesn't interest me much. My opinion is that you find a career that you will enjoy. If you enjoy your career, you will work harder at it, move up, make a name for yourself, and as IKC pointed out... eventually you will get out easier. No matter where you start off, you will most likely be last in line to take vacation for a few years so just concentrate on the career and hunt when you can.